有机电致发光材料与器件（OLEDs）

Design and synthesis of new organic light-emitting materials and their applications in organic light-emitting diodes (OLEDs)

有机场效应晶体管材料与器件（OFETs）

Design and synthesis of new organic semiconducting materials and their applications in organic field-effect transistors (OFETs)

有机太阳能电池材料与器件（OPVs）

Design and synthesis of new organic semiconducting materials and their applications in organic photovoltaics (OPVs)

有机近红外材料与光上转换探测器（NIR PDs）

Design and synthesis of new organic near-infrared (NIR) materials and their applications in optical upconverters (NIR PDs)

科研项目

一、国家级项目：

[1] 国家自然科学基金面上项目（61874170），二酰亚胺类双极性有机半导体材料的设计合成及其场效应性能研究，2019/01/01-2022/12/31，65万元，在研，项目负责人。

[2] 国家重点研发计划项目“新一代有机电致发光材料与器件”子课题5“显示器件集成技术与表征评价（2016YFB0401005），2016/07/01-2021/06/31，120万元，在研，项目负责人。

二、省部级项目：

[1] 陕西省科技厅项目（2018TD-030），液晶光学材料与器件研究创新团队，2018/01/01-2020/12/31，60万元，在研，项目参与人。

[2] 陕西省自然科学重点基金项目（2016JZ014），应用于全聚合物太阳能电池中的二酰亚胺类n型聚合物的设计和合成，2016/01/01-2018/12/31，10万元，已结题，项目负责人。

[3] 中央高校基本科研业务费专项资金（GK01010），创新团队资助项目, 有机光电子材料与器件，2016/01/01-2018/12/31，25万元，已结题，项目负责人。

[1] OLED材料开发，2020/12-2021/11，60万元，在研，项目负责人。

专利

[1] 胡鉴勇，赵振，冉会娟，一种芘类蓝色有机荧光材料的制备方法和应用，2020，CN202010174843.9

[2] 胡鉴勇，段雪伟，冉会娟，一种双蒽类D-δ-A型深蓝色有机荧光材料及其制备方法和应用，2020，CN202010121076.5

[3] 胡鉴勇，杨雪丽，段雪伟，赵振，一种芘基蓝色聚集诱导发光材料及其制备方法和应用，2019，CN201910340011.7

[4] 胡鉴勇， 段雪伟，赵振，一种近紫外色有机电致发光器件及其制备方法，2018，CN201811224370.8

[5] 胡鉴勇，张佳丽，赵振，段雪伟，一种D-A型有机蓝色荧光材料及其制备方法和应用，2018，CN201811619632.0

[6] 胡鉴勇，张佳丽，一种有机蓝色荧光材料的制备方法及其应用, 2018，CN201810118781.2

[7] 胡鉴勇，张佳丽，赵振，一种基于双蒽的D-A型有机蓝色荧光材料及其制备方法和应用，2018，CN201811620505.2

[8] 胡鉴勇，张佳丽，赵振，一种有机蓝色荧光材料及其制备方法和应用，2018，CN201811391082.1

[9] 胡鉴勇，张佳丽，赵振，段雪伟，一种基于双蒽的有机蓝色荧光材料及其制备方法和应用，2018，CN201811619631.6

[10] 胡鉴勇，杨雪丽， 一种基于萘的D-π-A型有机荧光材料及制备方法，2018，CN201810117911.0

[11] 夫 勇進，胡鉴勇，山下 裕介，城户 淳二，武田 孝，エキシマー特性を有する１，８-アリール置換ナフタレン誘導体及びこれを用いた有機ＥＬ素子 (日本专利，特許2011-29484, 公開JP2012167058-A号, 公开日：2012/09/06)

[12] 夫 勇進，胡鉴勇，城户 淳二，武田 孝，置換芳香族化合物、青色発光材料、有機EL素子 (日本专利，特許2013-239933,公開JP2014122212-A号, 公开日：2014/07/03)

近年来发表学术论文

2020年

32. Q. Wang, W. Gao, Y. Chen, X. Wang, J. Zeng, Y. Liu, H. Ran, Z. Hu, J. Bai, X. Feng,* C. Redshaw, Q. Chen,* J.-Y. Hu,* "Pyrene-fused dibenzoazatetracenes: synthesis, crystal structures, photophysical properties and their morphologies", Asian J. Org. Chem. 2020, DOI: 10.1002/ajoc.202000616.

31. H. Ran,^# Z. Zhao,^# X. Duan, F. Xie, R. Han, H. Sun, J.-Y. Hu,* "Blue-emitting butterfly-shaped donor-acceptortype 1,3,5,9-tetraarylpyrenes: easily available, low-cost conventional fluorophores for high-performance near ultraviolet electroluminescence with CIEy o 0.05", J. Mater. Chem. C 2020, DOI: 10.1039/d0tc03612a.

30. F. Xie,^# H. Ran,^# X. Duan, R. Han, H. Sun, J.-Y. Hu,* "1,3,5,9-Tetra(4-(1,2,2-triphenylvinyl) phenyl)pyrene (TTPE(1,3,5,9)Py): a prominent blue AIEgen for highly efficient nondoped pure-blue OLEDs", J. Mater. Chem. C 2020, DOI: 10.1039/d0tc04557h.

29. H. Ran, X. Duan, R. Zheng, F. Xie, L. Chen, Z. Zhao, R. Han, Z. Lei, J.-Y. Hu,* "Two Isomeric Azulene-Decorated Naphthodithiophene Diimidebased Triads: Molecular Orbital Distribution Controls Polarity Change of OFETs Through Connection Position", ACS Appl. Mater. Interfaces 2020, 12, 23225 (Supplementary Cover).

28. Y. Zhang, Y. Zheng, B. Wang, H. Ran, X. Wang, J.-Y. Hu, Q. Wang,* "Diphenylamine/triazine hybrids as bipolar hosts for phosphorescent organic light-emitting diodes", J. Mater. Chem. C 2020, 8, 4461.

27. X. Yang, Z. Zhao, H. Ran, J. Zhang, L. Chen, R. Han, X. Duan, H. Sun, J.-Y. Hu,* "New pyrene-based butterfly-shaped blue AIEgens: Synthesis, structure, aggregation-induced emission and their nondoped blue OLEDs", Dyes and Pigments 2020, 173, 107881.

2019年

26. B. Wang, H. Yang, Y. Zhang, G. Xie, H. Ran, T. Wang, Q. Fu, Y. Ren, N. Sun, G. Zhao, J.-Y. Hu, Q. Wang,* "Highly efficient electroluminescence from evaporation- and solution-processable orange–red thermally activated delayed fluorescence emitters", J. Mater. Chem. C, 2019, 7, 12321.

25. N. An,^# H. Ran,^# Y.. Geng, Q. Zeng, J.-Y. Hu,* J. Yang, Y. Sun,* X. Wang, E. Zhou,* "Exploring a Fused 2-(Thiophen-2-yl)thieno[3,2-b]thiophene (T-TT)Building Block to Construct n-Type Polymer for High-Performance All-Polymer Solar Cells", ACS Appl. Mater. Interfaces 2019, 11, 42412.

24. H. Ran, L. Chen, X. Yang, J. Zhang, Z. Zhao, R. Han, X. Duan, J.-Y. Hu,* "Arylacetylene end capped naphthodithiophene diimide (NDTI)-based semiconductors for air-stable, solution-processed n-channel organic fieldeffect transistors: Effect of terminal aryl groups on charge transport", Dyes and Pigments 2019, 169, 7.

23. C. Wu, B. Wang, Y. Wang, J.-Y. Hu, J. Jiang,* D. Ma, Q. Wang,* "A universal host material with a simple structure for monochrome and white phosphorescent/TADF OLEDs", J. Mater. Chem. C 2019, 7, 558.

2018年

22. A. Mahmood, J-.Y. Hu,* B. Xiao, A. Tang,* X. Wang, E. Zhou,* "Recent progress in porphyrin-based materials for organic solar cells", J. Mater. Chem. A 2018, 6, 16769.

21. R. Liu,^# H. Ran,^# Z. Zhao, X. Yang, J. Zhang, L. Chen, H. Sun, J.-Y. Hu,* "Synthesis and Optical Properties of Donor−Acceptor-Type 1,3,5,9-Tetraarylpyrenes: Controlling Intramolecular Charge-Transfer Pathways by the Change of π-Conjugation Directions for Emission Color Modulations", ACS Omega 2018, 3, 5866.

2017年

20. J. Yang, F. Chen, H. Ran, J.-Y. Hu, B. Xiao, A. Tang,* X. Wang, E. Zhou,* "Design and Synthesis of a Novel n-Type Polymer Basedon Asymmetric Rylene Diimide for the Application in All-Polymer Solar Cells", Macromol. Rapid Commun. 2017, 1700715.

19. C. Wu, Z. Wu, B. Wang, X. Li, N. Zhao J.-Y. Hu, D. Ma,* Q. Wang,* "Versatile Donor−π−Acceptor-Type Aggregation-Enhanced Emission Active Fluorophores as Both Highly Efficient Nondoped Emitter and Excellent Host", ACS Appl. Mater. Interfaces 2017, 9, 32946.

18. J. Li, Y. Liu, X. Ren, Z. Yang, R. Li, H. Su, X. Yang, J. Xu, H. Xu, J-.Y. Hu, A. Amassian, K. Zhao,* S. Liu,* "Solution Coating of Superior Large-Area Flexible Perovskite Thin Films with Controlled Crystal Packing", Adv. Optical Mater. 2017, 1700102.

17. C. Wu, Q. Guo, W. Ma, X. Li, P. Qiu, J.-Y. Hu, Q. Wang,* J. Chen, D. Ma,* "Hybrid host materials for highly efficient electrophosphorescence and thermally activated delayed fluorescence independent of the linkage mode", Phys. Chem. Chem. Phys. 2017, 19, 5177.

2016年前代表性论文

16. X. Feng, J.-Y. Hu, C. Redshaw, T. Yamato,* "Functionalization of Pyrene To Prepare Luminescent Materials—Typical Examples of Synthetic Methodology", Chem. Eur. J. 2016, 22, 11898.

15. X. Feng, H. Tomiyasu, J.-Y. Hu,* X. Wei, C. Redshaw, M. R. J. Elsegood, L. Horsburgh, S. J. Teat, T. Yamato,* "Regioselective Substitution at the 1,3- and 6,8-Positions of Pyrene for the Construction of Small Dipolar Molecules", J. Org. Chem. 2015, 80, 10973.

14. J.-Y. Hu,* M. Nakano, I. Osaka, and K. Takimiya,* "Naphthodithiophenediimide (NDTI)-Based Triads for High-Performance Air-Stable, Solution-Processed Ambipolar Organic Field-Effect Transistors", J. Mater. Chem. C. 2015, 3, 4244.

13. X. Feng, J.-Y. Hu, H. Tomiyasu, Z. Tao, C. Redshaw, M. R. J. Elsegood, L. Horsburgh, S. J. Teat, X.-F. Wei, T. Yamato,* "Iron(III)bromide-catalyzed bromination of 2-tert-butylpyrene and corresponding positions-dependent aryl-functionalized pyrene derivatives", RSC Advance. 2015, 5, 8835.

12. J.-Y. Hu, Y.-J. Pu,* F. Satoh, S. Kawata, H. Katagiri, H. Sasabe, J. Kido,* "Bisanthracene-Based Donor-Acceptor type Light-Emitting Dopants: Highly Efficient Deep-Blue Emission in Organic Light-Emitting Devices", Adv. Funct. Mater. 2014, 24, 2064.

11. X. Feng, J.-Y. Hu,* F. Iwanaga, N. Seto, C. Redshaw, M. R. J. Elsegood, T. Yamato,* "Synthesis and photophysical properties of novel butterfly-shaped blue emitters based on pyrene", Org. Biomol. Chem. 2013, 11, 8366.

10. Fukutomi, M. Nakano, J.-Y. Hu, I. Osaka, and K. Takimiya,* "Naphthodithiophenediimide (NDTI): Synthesis, Structure, and Applications", J. Am. Chem. Soc. 2013, 135, 11445.

9. X. Feng, F. Iwanaga, J.-Y. Hu,* H. Tomiyasu, M. Nakano, C. Redshaw, Mark R. J. Elsegood, T. Yamato,* "An efficient approach to the synthesis of novel pyrene-fused azaacenes", Org. Lett., 2013, 15, 3594.

8. J.-Y. Hu, X. Feng, A. Paudel, U. Rayhan, H. Tomiyasu, P. Thuery, M. R. J. Elsegood, C. Redshaw, T. Yamato,* "Synthesis, Structural and Photophysical Properties of First Member of New Class of Pyrene Based [4]Helicenes", Eur. J. Org. Chem. 2013, 5829.

7. J.-Y. Hu, Y.-J. Pu,* Y. Yamashita, F. Satoh, S. Kawata, H. Sasabe, J. Kido,* "Excimer-emitting single molecules with stacked p-conjugated groups covalently linked at the 1,8-positions of naphthalene for highly efficient organic light-emitting devices", J. Mater. Chem. C. 2013, 1, 3871.

6. X. Feng, J.-Y. Hu,* F. Iwanaga, N. Seto, C. Redshaw, M. R. J. Elsegood, T. Yamato,* "Blue-Emitting Butterfly-Shaped 1,3,5,9-Tetraarylpyrenes: Synthesis, Crystal Structures and Physical Properties", Org. Lett. 2013, 15, 1318.

5. J.-Y. Hu, X. Feng, N. Seto, F. Iwanaga, M. Era, T. Matsumoto, J. Tanaka, T. Yamato,* "Synthesis, crystal structure and photophysical properties of 7-tert-butyl-5-mono- and 5,9-bis-(4-methoxyphenylethynyl)-1,3-dimethylpyrene", J. Lumin. 2013, 141, 111.

4. J.-Y. Hu,* A. Paudel, N. Seto, X. Feng, M. Era, T. Matsumoto, J. Tanaka, M. R. J. Elsegood, C. Redshaw, T. Yamato,* "Pyrene-Cored Blue-Light Emitting [4]Helicenes: Synthesis, Crystal Structures and Photophysical Properties", Org. Biomol. Chem. 2013, 11, 2186.

3. X. Feng, J.-Y. Hu,* L. Yi, N. Seto, F. Iwanaga, Z. Tao, C. Redshaw, T. Yamato,* "Pyrene-Based Y-shaped Solid State Blue Emitters: Synthesis, Characterization and Photoluminescence", Chem.-Asian J. 2012, 7, 2854.

2. J.-Y. Hu, Y.-J. Pu,* G. Nakata, S. Kawata, H. Sasabe, J. Kido,* "A single-molecule excimer-emitting compound for highly efficient fluorescent organic light-emitting devices", Chem. Commun. 2012, 48, 8434.

1. J.-Y. Hu,* X.-L. Ni, X. Feng, M. Era, M. R. J. Elsegood, S. J. Teat, T. Yamato,* "Highly Emissive Hand-Shaped p-Conjugated Alkynylpyrenes: Synthesis, Structures, and photophysical properties", Org. Biomol. Chem. 2012, 10, 2255.